The formula
C = A₂₆₀ × factor × dilution
What it means
Nucleic acids absorb most strongly at 260 nanometres, and in the range where the Beer-Lambert law holds, absorbance is proportional to concentration. The constant of proportionality depends on what the sample is: an absorbance of 1 corresponds to about 50 ng/µl of double-stranded DNA, 40 of RNA and 33 of a single-stranded oligonucleotide. Proteins absorb at 280, so the ratio between the two readings measures how clean the preparation is.
How to work it out by hand
- Measure the absorbance at 260 nm, blanked against the same buffer
- Multiply by the factor for the nucleic acid you are measuring
- Multiply by the dilution if you measured a diluted sample
- Divide the 260 reading by the 280 one to check purity
What is worth knowing
The measurement is only reliable with an absorbance at 260 between 0.1 and 1: below that noise takes over and above it the detector saturates, and in both cases you have to dilute and measure again. A 260/280 ratio around 1.8 is good for DNA and 2.0 for RNA; below 1.7 there is protein or phenol. And this measures everything that absorbs at 260, not only what you care about: free nucleotides and contaminating RNA count the same, so a high concentration does not mean the DNA is intact.